Refractory dissolved organic matter (DOM), highly resistant to microbial degradation, has persisted in the ocean for thousands of years and has accumulated to one of the largest pools of reduced carbon on earth's surface. This material could provide an important feedback mechanism in the climate system, because minor changes in the DOM pool would considerably impact atmospheric CO 2 and the radiation balance on earth.
Recent progress in analytical chemistry has allowed the characterisation of DOM at the molecular level in unprecedented detail, revealing new insights into its source and history. We aim to understand the molecular structure-function relationships for DOM and other organic matter pools in order to understand earth's past and future.